For the conversions
I will start with pressure
1atm=101.3kPa
x =700kPa
x=700kPa/101.3kPa
x=6.91atm
Temperature
273K+30.00C
303K
Volume
1L=1000ml
x =50ml
x=0.05L
PV=nRT
6.91*0.05=n*0.08206*303
0.3455=24.86418n
0.3455/24.86418=n
0.0138=n
number of moles = 0.0138moles
Note: 0.08206 is the gas constant in this case
