sydneypeter1330 sydneypeter1330
  • 06-03-2018
  • Chemistry
contestada

Hydroxylamine is a weak molecular base with kb = 6.6 x 10-9. what is the ph of a 0.0500 m solution of hydroxylamine?

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Dejanras
Dejanras Dejanras
  • 15-03-2018
Answer is: pH of hydroxylamine solution is 9,23.

Kb(NH₂OH) = 1,8·10⁻⁵.
c
₀(NH₂OH) = 0,0500 M = 0,05 mol/L.
c(NH
₂⁺) = c(OH⁻) = x.

c(NH₂OH) = 0,05 mol/L - x.
Kb = c(NH
₂⁺) · c(OH⁻) / c(NH₂OH).

0,0000000066 = x² /  (0,05 mol/L - x). 

solve quadratic equation: x = c(OH⁻) = 0,000018 mol/L.
pOH = -log(
0,000018 mol/L) = 4,74.
pH = 14 - 4,74 = 9,23.


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